Basically, stars are big exploding balls of gas, mostly hydrogen and helium. Our nearest star, the Sun, is so hot that the huge amount of hydrogen is undergoing a constant star-wide nuclear reaction, like in a hydrogen bomb.
Why do the stars twinkle?
Stars twinkle because of turbulence in the atmosphere of the Earth. As the atmosphere churns, the light from the star is refracted in different directions. This causes the star's image to change slightly in brightness and position, hence "twinkle." Planets do not twinkle the way stars do...

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